In Road to 2002, Barcelona or "Barca" is the team Tsubasa wants to join (Road to 2002 arc, chapter 2, pages 40-41).
However, he is in competition with Rivaul since they're playing in the same spot (Road to 2002 arc, chapter 8, page 9).
As a result, Tsubasa will first prove himself in Barca's B team (Road to 2002 arc, chapter 18), and only join the top team (Road to 2002 arc, chapter 74) when Rivaul becomes injured (Road to 2002 arc, chapter 72).

Liga winner (before Road to 2002, at least once) (Road to 2002 arc, chapter 126, page 5)
Copa del Rey winner (Road to 2002 arc, chapter 126, page 5)
Various titles winner (Road to 2002 arc, chapter 126, page 5)
Draw 2-2 against Valencia (home, Camp Nou) (Road to 2002 arc, chapter 53, pages 3-4)
Defeat against Numancia (away, Los Pajaritos) (Road to 2002 arc, chapter 72, page 8)
Defeat 2-3 against Rayo Vallecano (home, Camp Nou) (Road to 2002 arc, chapter 72, page 1)
Defeat 0-3 against Celta (away, Balaídos) (Road to 2002 arc, chapter 72, page 10)
Victory 6-5 against R. Madrid (home, Camp Nou) (Road to 2002 arc, chapter 142, pages 10-11)
Victory 2-0 against Valladolid (away, José-Zorrilla) (Golden-23 arc, chapter 9, page 8)
Victory at least 3-1 against Sevilla (home, Camp Nou) (Golden-23 arc, chapters 34-35)
Victory (Golden-23 arc, chapter 54, page 18)
Victory (Golden-23 arc, chapter 54, page 18)
Victory (Golden-23 arc, chapter 54, page 18)
Victory (Golden-23 arc, chapter 54, page 18)
Victory (Golden-23 arc, chapter 54, page 18)
Victory (Golden-23 arc, chapter 54, page 18)
Victory (Golden-23 arc, chapter 54, page 18)
Victory 3-2 against Valencia (away, Mestalla) (Golden-23 arc, chapter 67, pages 2-3)
Victory 3-0 against Celta (home, Camp Nou) (Golden-23 arc, chapter 73, page 4)
Victory 2-1 against A. Madrid (home, Camp Nou) (Golden-23 arc, chapter 77, pages 8-9)
Draw 2-2 against R. Madrid (away, Santiago Bernabeu) (Oversea fierce fights en la liga arc, chapter 55, pages 5-6)
Victory 2-1 against Espanyol (home, Camp Nou) (Oversea fierce fights en la liga arc, chapter 55, pages 5-6)
Victory 1-0 against Deportivo (away, Riazor) (Oversea fierce fights en la liga arc, chapter 58, pages 10 to 15)
Victory 3-1 against Granada (home, Camp Nou) (Rising sun arc, chapter 1, pages 45-46)
Liga winner (Rising sun arc, chapter 1, pages 49-50)

Players

ライカール
Luikal
FW (n°9)

オーフェルス
Overus
FW (n°11)

サビッシュ
Savishe
FW (n°19)

ネトォ
Neto'o
FW (n°27)

リバウール
Rivaul
MF (n°10)

大空 翼
Oozora Tsubasa
MF (n°28)

セモン
Semon
MF (n°12)

ルイス エンポリ
Luis Enpoli
MF (n°21)

フィリップ コトゥ
Phillip Cotu
MF (n°8)

シャービ
Xavii
MF (n°16)

イエニスタ
Ienista
MF (n°24)

ジョゼップ
グランディオス
Josep Grandios
MF (n°4, captain)

アラベルド
Alaberdo
MF (n°7)

ペドロ フォンセカ
Pedro Fonseca
DF (n°6)

マルコス
アウミージャ
Marcos Almieja
DF (n°15)

プティーニ
Putini
DF (n°5)

ゴルドバ ゴンザレス
Gordoba Gonzales
DF (n°2)

パジョル
Payol
DF (n°24)

レシャール
Rechard
GK (n°1)

バルテス
Valtes
GK (n°25)

エリック
ファンサール
Erick Van Saal
Head coach

モウラ
Moura
Keeper coach

For more informations, check their detailed playstyle.

There are other players named Marono, Serbio, Tomas, Helis and Carmona (Road to 2002 arc, chapter 10, page 6).

Tsubasa only joined the team for the first trainings, then the first Clasico.

Rivaul on the other hand didn't play many matches, or only played for a bit because of an injury, coming back to play full time starting from the second clasico.

When Grandios wasn't playing, Cotu was wearing the captain's armband (Golden-23 arc, chapter 73, pages 9-10).